exopolysaccharide, EPS

capsular polysaccharide and ropy polysaccharide

Exopolysaccharides are high-molecular-weight polymers that are composed of sugar residues and are secreted by a microorganism into the surrounding environment. Microorganisms synthesize a wide spectrum of multifunctional polysaccharides including intracellular polysaccharides, structural polysaccharides and extracellular polysaccharides or exopolysaccharides (EPS). Exopolysaccharides generally constitute of monosaccharides and some non-carbohydrate substituents (such as acetate, pyruvate, succinate, and phosphate). Owing to the wide diversity in composition, exopolysaccharides have found multifarious applications in various food and pharmaceutical industries. Many microbial EPS provide properties that are almost identical to the gums currently in use. With innovative approaches, efforts are underway to supersede the traditionally used plant and algal gums by their microbial counterparts. Moreover, considerable progress has been made in discovering and developing new microbial EPS that possess novel industrial significance.

The sensory benefits of the exopolysaccharides of lactic acid bacteria are well established and there is evidence for the health properties that are attributable to exopolysaccharides from lactic acid bacteria.

Capsular exopolysaccharides can protect pathogenic bacteria and contribute to their pathogenicity. Attachment of nitrogen-fixing bacteria to plant roots and soil particles, which is important for colonisation of rhizosphere and roots and for infection of the plant, can be mediated by exopolysaccharides. An example for industrial use of exopolysaccharides is the application of dextran in panettone and other breads in the bakery industry.